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• ChitChatting.com
  Here's a free browser-based chat service that offers lots of features and has chat rooms for teens and adults. The service is easy to use: just pick an avatar icon and start chatting away.
  
  
• Chatzy 
  Need a quick way to chat with your friends? Here's a top-notch free service that lets you easily create your own chat room, in which you can invite people via E-mail to chat. No installation or registration is required and the service doesn't pester you with banner ads or popups.  
  
  
• Chat-Place.org
  This is a popular chat room site that is aimed at teens. Here, you'll find Java-based chat rooms in a variety of languages, as well as Webcam chat, online games, and other fun free goodies for teens.
  
  
• ScholarStuff.com 
  Free chat @ ScholarStuff.com with hundreds of people all over the country & the globe. 
  
  
• BYF Chat  
  This free service offers family friendly chat rooms with voice and cam options. You can also set up your own local chat room here, as well. The site also offers over 2,500 free online games.
  
  
• ChatJungle.com  
  Here's a good place to go if you're looking to chat online. A popular site, ChatJungle.com offers lots of categorized chat rooms, including dating chat, gaming chat, senior chat, teen chat, and more. Chat rooms here include audio and visual conference capability and feature collaborative features like file sharing, image upload and more.
  
  
• MSN Avatars.net        
  This site offers a nice selection of free avatars, emoticons and display pictures for use with MSN Messenger, the instant messaging client.
  
  
• CyberNet Worlds.com  
  Immerse yourself in the fascinating world of 3D chat with CyberNet Worlds' free 3D chat browser. Here, you can roam around various colorful 3D landscapes, chatting with users from around the world and build your own virtual home. The CyberNet community also stages social events, parties and contests. (For Windows).
  
  
• Active Worlds 3D Chat       
  We think that this is one of the coolest freeware programs on the Web. It's a browser that lets you access AlphaWorld, a unique, 3D virtual community populated by real people. The Active Worlds universe boasts thousands of users who you can chat with. You can explore over 100 worlds in real-time, high-color graphics. You can even own land and create buildings on your property, from a simple house to an elaborate palace. (Available for Windows, Macs and Linux).